Chemistry of Iron, Cobalt and Nickel (eBook)

Front Cover 1
The Chemistry of Iron, Cobalt and Nickel 4
Copyright Page 5
Table of Contents 6
PREFACE 8
INDEX 10
PART 40: 
14 
CHAPTER 1. THE ELEMENT 14
1.1. HISTORY 14
1.2. OCCURRENCE AND DISTRIBUTION 14
1.3. IRON AND STEEL MANUFACTURE 15
1.4. PREPARATION OF PURE IRON 17
1.5. ALLOTROPY OF IRON 17
1.6. NUCLEAR PROPERTIES 18
1.7. PHYSICAL PROPERTIES 19
1.8. CHEMICAL PROPERTIES 20
1.9. BIOLOGICAL IMPORTANCE OF IRON COMPOUNDS 
21 
1.10. ANALYTICAL CHEMISTRY OF IRON 22
1.11. ALLOYS OF IRON 23
CHAPTER 2. COMPOUNDS OF IRON IN LOW OXIDATION STATES ( -2 , -1 , 0, +1) 24
2.1. IRON CARBONYLS 24
2.2. NITRIC OXIDE COMPLEXES OF IRON 35
2.3. OTHER COMPOUNDS OF IRON IN LOW OXIDATION STATES 40
CHAPTER 3. COMPOUNDS OF IRON (II) 40
3.1. GENERAL AND REDOX CONSIDERATIONS 40
3.2. SIMPLE SALTS OF IRON(II) 42
3.3. ORGANOMETALLIC COMPOUNDS OF IRON 46
3.4. COMPLEXES OF IRON(II) 61
CHAPTER 4. COMPOUNDS OF IRON(III) 73
4.1. SIMPLE COMPOUNDS AND SALTS OF IRON(III) 73
4.2. COMPLEX COMPOUNDS OF IRON(III) 77
4.3. ELECTRONIC STRUCTURES OF IRON(III) COMPLEXES 83
CHAPTER 5. COMPOUNDS OF IRON IN HIGH OXIDATION STATES (+4, +5, +6) 84
5.1. IRON(IV) COMPOUNDS 84
5.2. IRON(V) COMPOUNDS 85
5.3. IRON(VI) COMPOUNDS 85
PART 
88 
CHAPTER 1. THE ELEMENT 88
1.1. HISTORY 88
1.2. OCCURRENCE AND DISTRIBUTION 88
1.3. INDUSTRIAL PRODUCTION OF COBALT 88
1.4. ALLOTROPY OF COBALT 89
1.5. NUCLEAR PROPERTIES 
89 
1.6. PHYSICAL PROPERTIES 90
1.7. CHEMICAL PROPERTIES 91
1.8. BIOLOGICAL IMPORTANCE OF COBALT COMPOUNDS 91
1.9. THE ANALYTICAL CHEMISTRY OF COBALT 92
1.10. ALLOYS OF COBALT 93
CHAPTER 2. COMPOUNDS OF COBALT IN LOW OXIDATION STATES ( -1 , 0 , +1) 94
2.1. COBALT CARBONYLS 94
2.2. COBALT NITROSYLS 99
2.3. OTHER COMPLEXES OF COBALT IN LOW OXIDATION STATES 102
CHAPTER 3. COMPOUNDS OF COBALT(II) 103
3.1. GENERAL AND REDOX CONSIDERATIONS 103
3.2. SIMPLE COMPOUNDS OF COBALT(II) 104
3.3. ORGANOMETALLIC COMPOUNDS OF COBALT 108
3.4. COMPLEXES OF COBALT(II) 115
CHAPTER 4. COMPOUNDS OF COBALT(III) 128
4.1. SIMPLE COMPOUNDS AND SALTS OF COBALT(III) 128
4.2. COMPLEX COMPOUNDS OF COBALT(III) 130
CHAPTER 5. COMPOUNDS OF COBALT IN HIGH OXIDATION STATES (+4, +5) 142
PART 42: 
144 
CHAPTER 1. THE ELEMENT 144
1.1. HISTORY 
144 
1.2. OCCURRENCE AND DISTRIBUTION 144
1.3. INDUSTRIAL PRODUCTION OF NICKEL 145
1.4. PREPARATION OF PURE NICKEL 145
1.5. NUCLEAR PROPERTIES 146
1.6. PHYSICAL PROPERTIES 146
1.7. CHEMICAL PROPERTIES 147
1.8. ANALYTICAL CHEMISTRY 148
1.9. ALLOYS OF NICKEL 149
CHAPTER 2. COMPOUNDS OF NICKEL IN LOW OXIDATION STATES ( -1, 0, +1) 150
2.1. NICKEL CARBONYL, Ni(CO) 150
2.2. NICKEL NITROSYLS30 154
2.3. COMPLEX CYANIDES AND ISOCYANIDES 156
2.4. PHOSPHINE COMPLEXES 158
CHAPTER 3. COMPOUNDS OF NICKEL(II) 159
3.1. GENERAL AND REDOX CONSIDERATIONS 159
3.2. SIMPLE COMPOUNDS OF NICKEL(II) 160
3.3. ORGANOMETALLIC COMPOUNDS OF NICKEL 
166 
3.4. COMPLEXES OF NICKEL(II) 174
CHAPTER 4. COMPOUNDS OF NICKEL IN HIGH OXIDATION STATES ( +3, +4) 194
4.1. SIMPLE COMPOUNDS OF NICKEL(III) AND NICKEL(IV) 194
4.2. COMPLEXES OF NICKEL(III) 195
4.3. COMPLEXES OF NICKEL(IV) 195
INDEX 10
Contents of Comprehensive Inorganic Chemistry 198
INDEPENDENT OPINION 200