Verified Synthesis of Zeolitic Materials (eBook)

Cover 1
Table of contents 4
Preface 6
Synthesis commission: membership 7
Introduction and explanatory notes 8
Conditions for recording of XRD patterns 12
Contributors 13
Part I: Introduction to zeolite synthesis 24
Chapter 1. Source materials for zeolite synthesis 24
Chapter 2. Nucleation. growth. and seeding in zeolite synthesis 26
Chapter 3. Synthesis of high-silica zeolites and phosphate-based materials in the presence of fluorides 30
Chapter 4. Templating in molecular sieve synthesis 32
Chapter 5. The pH value and its importance for the crystallization of zeolites 38
Chapter 6. Microwave technology in zeolite synthesis 44
Chapter 7. Preparation of zeolite membranes 48
Chapter 8. Safety considerations for zeolite synthesis 50
Chapter 9. Product characterization by x-ray powder diffraction 52
Chapter 10. Determination of the elemental compositor of zeolitic materials 56
Chapter 11.Characterization of zeolites by SEM 60
Chapter 12. Product characterization by NMR 62
Chapter 13. Characterization of zeolites by sorption capacity measurements 66
Chapter 14. Ion-exchange capacity 72
Chapter 15. Characterization by IR spectroscopy 74
Chapter 16. How to read a patent 78
Part II: Synthesis recipes 79
Chapter 17. ABW - Li-A (BW) 79
Chapter 18. AEI - AlPO4-18 83
Chapter 19. AEI - SAPO-18 (DPEA method) 86
Chapter 20. AEI - SAPO-18 (TEA method) 89
Chapter 21. AEL - AlPO4-11 92
Chapter 22. AFI - AlPO4-5 95
Chapter 23. AFI - SAPO-5 98
Chapter 24. AFI - COAPO-5 101
Chapter 25. AFI - SSZ-24 104
Chapter 26. AFO - SAPO-41 107
Chapter 27. AFS - MAPO-46 110
Chapter 28. ANA - Analcime 112
Chapter 29. AST - AlPO4-16 115
Chapter 30. ATN - MAPO-39 118
Chapter 31. BEA - Zeolite Beta 120
Chapter 32. BEA - [Ti, Al] Beta 123
Chapter 33. CAN - Cancrinite 126
Chapter 34. CHA - Chabazite 128
Chapter 35. CHA - SSZ-13 131
Chapter 36. CHA - SAPO-34 134
Chapter 37. CHA - SAPO-44 137
Chapter 38. -CLO - Cloverite (GaPO4) 139
Chapter 39. EAB - TMA-E 142
Chapter 40. EDI - Barrer K-F 145
Chapter 41. EDI - Linde Type F 147
Chapter 42. EMT - EMC-2 150
Chapter 43. EUO - [Ga] EU-1 152
Chapter 44. FAU - Linde Type X 155
Chapter 45. FAU - Low-silica Type X ( LSX ) 158
Chapter 46. FAU - Linde Type Y 161
Chapter 47. FAU - High-silica Faujasite EMC-1 164
Chapter 48. FAU - [Ga] Type Y 167
Chapter 49. FAU - SAPO-37 169
Chapter 50. FER - ZSM-3 5 172
Chapter 51. GIS - Zeolite P 174
Chapter 52. KFI - ZK-5 176
Chapter 53. KFI - High-silica KFI 179
Chapter 54. LEV - [B]-Levyne 182
Chapter 55. LTA - Linde Type A 184
Chapter 56. LTA - ZK-4 187
Chapter 57. LTA - Zeolite Alpha 190
Chapter 58. LTA - GaPO4 193
Chapter 59. LTL - Linde Type L 195
Chapter 60. MAZ - Mazzite 198
Chapter 61. MER - Linde W 201
Chapter 62. MFI - High-alumina ZSM-5 203
Chapter 63. MFI - Silicalite-l 206
Chapter 64. MFI - [B] ZSM-5 208
Chapter 65. MFI - [Fe] ZSM-5 210
Chapter 66. MFI - [Ti] ZSM-5 212
Chapter 67. MFI - [Ti, Al] ZSM-5 214
Chapter 68. MOR - Mordenite 217
Chapter 69. MTN - ZSM-39 219
Chapter 70. MTT - ZSM-23 222
Chapter 71. MTW - ZSM-12 225
Chapter 72. MTW- [Ga] ZSM-12 227
Chapter 73. MWW - MCM-22 230
Chapter 74. NAT - [Ga] Natrolite 233
Chapter 75. OFF - Linde Type T 235
Chapter 76.OFF - Offretite 238
Chapter 77. OFF - [Ga] Offretite 241
Chapter 78. PAU - ECR-18 244
Chapter 79. PAU - Paulingite (seeded) 246
Chapter 80. PHI - Phillipsite 249
Chapter 81. PHI - High-alumina Phillipsite 251
Chapter 82. RHO - High-silica Rho 254
Chapter 83. SOD - NaBr-Sodalite 256
Chapter 84. STT - SSZ-23 260
Chapter 85. TON - ZSM-22 263
Chapter 86. VFI - VPI-5 (DPA method) 266
Chapter 87. VFI - VPI-5 (TBA method) 268
Chapter 88. -SUZ-4 270