Extractive Metallurgy of Activated Minerals -  P. Balaz

Extractive Metallurgy of Activated Minerals (eBook)

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2000 | 1. Auflage
292 Seiten
Elsevier Science (Verlag)
978-0-08-053153-3 (ISBN)
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Mechanical activation of solids is a part of mechanochemistry, the science with a sound theoretical foundation exhibiting a wide range of potential application. Mechanical activation itself is an innovative procedure where an improvement in technological processes can be attained via a combination of new surface area and defects formation in minerals.
Mechanical activation is of exceptional importance in extractive metallurgy and mineral processing and this area forms the topic of this book and is the result of more than twenty years of research and graduate teaching in the field.
In pyrometallurgy, the mechanical activation of minerals makes it possible to reduce their decomposition temperatures or causes such a degree of disordering that the thermal activation may be omitted entirely. The potential mitigation of environmental pollutants is becoming increasingly important in this context.
The lowering of reaction temperatures, the increase of the rate and amount of solubility, preparation of water soluble compounds, the necessity for simpler and less expensive reactors and shorter reaction times are some of the advantages of mechanical activation in hydrometallurgy. The environmental aspects of these processes are particularly attractive.
Several industrial processes are examined and their flowsheets are presented as succesful of activation. In these processes, the introduction of a mechanical activation step into the technological cycle significantly modifies the subsequent steps.
The book is designed for researchers, teachers, operators and students in the areas of extractive metallurgy, mineral processing, mineralogy, solid state chemistry and materials science.It will encourage newcomers to the mechanochemistry to do useful research and discover novel applications in this field.

Mechanical activation of solids is a part of mechanochemistry, the science with a sound theoretical foundation exhibiting a wide range of potential application. Mechanical activation itself is an innovative procedure where an improvement in technological processes can be attained via a combination of new surface area and defects formation in minerals. Mechanical activation is of exceptional importance in extractive metallurgy and mineral processing and this area forms the topic of this book and is the result of more than twenty years of research and graduate teaching in the field. In pyrometallurgy, the mechanical activation of minerals makes it possible to reduce their decomposition temperatures or causes such a degree of disordering that the thermal activation may be omitted entirely. The potential mitigation of environmental pollutants is becoming increasingly important in this context. The lowering of reaction temperatures, the increase of the rate and amount of solubility, preparation of water soluble compounds, the necessity for simpler and less expensive reactors and shorter reaction times are some of the advantages of mechanical activation in hydrometallurgy. The environmental aspects of these processes are particularly attractive. Several industrial processes are examined and their flowsheets are presented as succesful of activation. In these processes, the introduction of a mechanical activation step into the technological cycle significantly modifies the subsequent steps. The book is designed for researchers, teachers, operators and students in the areas of extractive metallurgy, mineral processing, mineralogy, solid state chemistry and materials science.It will encourage newcomers to the mechanochemistry to do useful research and discover novel applications in this field.

Front Cover 1
Extractive Metallurgy of Activated Minerals 4
Copyright Page 5
CONTENTS 8
INTRODUCTION 14
CHAPTER 1 . MECHANOCHEMISTRY AND MECHANICAL ACTIVATION OF SOLIDS 16
1.1 History of mechanochemistry 18
1.2. Theories of mechanochemistry 19
1.3. Mechanical activation 24
1.4. Equipments for mechanical activation 26
1.5. References 28
CHAPTER 2 . SELECTED METHODS FOR THE IDENTIFICATION OF CHANGES IN MECHANICALLY ACTIVATED SOLIDS 30
2.1. Infrared spectroscopy 32
2.2. Photoelectron spectroscopy 34
2.3. Electron paramagnetic resonance 37
2.4. Mössbauer spectroscopy 39
2.5. X-ray diffraction 42
2.6. References 46
CHAPTER 3 . PHYSICO-CHEMICAL PROPERTIES OF MECHANICALLY ACTIVATED MINERALS 50
3.1. Disintegration of particles 52
3.2. Formation of new surface area and effect of aggregation 56
3.3. Disordering of crystal structure 62
3.4. Relationship between new surface area formation and disordering of crystal structure 63
3.5. Physical and chemical changes of minerals during mechanical activation in organic liquids 65
3.6. Mechanochemical surface oxidation 68
3.7. Paramagnetic centres in mechanically activated minerals 84
3.8. Mössbauer effect in mechanically activated minerals 89
3.9. References 92
CHAPTER 4. POLYMORPHOUS TRANSFORMATIONS INDUCED IN MINERALS BY MECHANICAL ACTIVATION 96
4.1. Chalcopyrite CuFeS2 98
4.2. Zinc sulfide ZnS 101
4.3. Cinnabar HgS 102
4.4. Greenockite CdS 105
4.5. References 107
CHAPTER 5. THERMAL DECOMPOSITION OF MECHANICALLY ACTIVATED MINERALS 110
5.1. Oxidative decomposition 112
5.2. Decomposition in an inert atmosphere (pyrolysis) 127
5.3. Reductive decomposition 144
5.4. Solid state exchange reactions 153
5.5. References 154
CHAPTER 6. CHEMICAL LEACHING OF MECHANICALLY ACTIVATED MINERALS 158
6.1. Acid oxidizing leaching 161
6.2. Acid non-oxidizing leaching 180
6.3. Alkaline leaching 186
6.4. Leaching of sulfides containing gold and silver 193
6.5. Electrochemical aspects of leaching of mechanically activated sulfides 197
6.6. References 203
CHAPTER 7. INFLUENCE OF MECHANICAL ACTIVATION ON BACTERIAL LEACHING OF MINERALS 210
7.1. Chalcopyrite CuFeS2 212
7.2. Arsenopyrite FeAsS 215
7.3. Pyrite FeS2 216
7.4. Sphalerite ZnS 220
7.5. Tetrahedrite CUl2Sb4SI3 225
7.6. References 226
CHAPTER 8. MECHANICAL ACTIVATION IN TECHNOLOGY 228
8.1. Effect of mechanical activation on flotability of minerals 230
8.2. Mechanical activation as pretreatment step for oxidative leaching 231
8.3. Mechanical activation as pretreatment step for gold and silver extraction 250
8.4. Mechanochemical leaching 260
8.5. Mechanical activation as a way of metallurgical waste treatment 268
8.6. Economic evaluation of mechanical activation 270
8.7. Sorption of metals from solutions by mechanically activated minerals 272
8.8. References 273
SUMMARY 280
AUTHOR INDEX 282
SUBJECT INDEX 289

Erscheint lt. Verlag 28.4.2000
Sprache englisch
Themenwelt Naturwissenschaften Chemie Physikalische Chemie
Naturwissenschaften Geowissenschaften Geologie
Naturwissenschaften Geowissenschaften Mineralogie / Paläontologie
Technik Maschinenbau
ISBN-10 0-08-053153-9 / 0080531539
ISBN-13 978-0-08-053153-3 / 9780080531533
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