Advances in Inorganic Chemistry and Radiochemistry (eBook)

Front Cover 1
Advances in Inorganic Chemistry and Radiochemistry, Volume 13 4
Copyright Page 5
Contents 6
List of Contributors 8
Contents of Previous Volumes 10
Chapter 1. Zirconium and Hafnium Chemistry 16
I. Introduction 16
II. Compounds Containing Metal–Hydrogen Bonds 17
III. Compounds Containing Metal–Carbon Bonds 20
IV. Compounds with Metal–Nitrogen, Metal–Phosphorus, or Metal–Arsenic Bonds 31
V. Compounds with Metal–Oxygen or Metal–Sulfur Bonds 45
VI. Compounds with Metal–Halogen Bonds 100
References 130
Chapter 2. Electron Spin Resonance of Transition Metal Complexes 150
I. Introduction 151
II. Principles of Electron Spin Resonance 152
III. Hyperfine Coupling 164
IV. Spin–Orbit Coupling and the Significance of the g Tensor 193
V. The Case of Two or More Unpaired Electrons: Fine Structure 208
VI. Linewidths and Relaxation Mechanisms 220
VII. Experimental Technique 223
VIII. Discussion of the Literature 242
References 356
Chapter 3. Recent Progress in the Chemistry of Fluorophosphines 378
I. Introduction 379
II. Trifluorophosphine 379
III. Fluorophosphines Containing Phosphorus–Carbon Bonds. Alkyl-or Arylfluorophosphines, RnPF3-n 382
IV. Halogeno- and Pseudohalogenofluorophosphines 393
V. Fluorophosphines Containing Phosphorus–Nitrogen Bonds 398
VI. Fluorophosphines Containing Phosphorus–Oxygen Bonds (Fluorophosphites) 412
VII. Other Fluorophosphines 421
VIII. Coordination Complexes 425
IX. Transition Metal–Fluorophosphine Complexes 429
X. Other Fluorophosphine Complexes 454
XI. Nuclear Magnetic Resonance Spectra 462
References 475
Chapter 4. Transition Metal Clusters with .-Acid Ligands 486
I. Introduction 486
II. Survey of Transition Metal Cluster Compounds 488
III. Physical Properties of Clusters 512
IV. Reactivity of Clusters 521
V. Bonding and Electronic Structure of Clusters 533
References 536
Supplementary References 547
Author Index 550
Subject Index 590