Advances in Organometallic Chemistry (eBook)

Front Cover 1
Advances in Organometallic Chemistry, Volume 10 4
Copyright Page 5
Contents 6
List of Contributors 10
Chapter 1. My Way in Organometallic Chemistry 12
I. First Steps 12
II. The Diazonium Method 14
III. Homolysis and Heterolysis of Diazonium Salts. Synthesis of Halogenonium Salts. The Halogenonium Method 17
IV. Early Investigations into Organometallic Exchange Reactions 20
V. Quasi-Complex Compounds 21
VI. Investigation of the Grignard Reaction 25
VII. Organometallic Tautomerism and Dual Reactivity 26
VIII. Fragmentation 33
IX. Stereochemistry of s, s- and s, p-Conjugations 34
X. Stereochemistry of Electrophilic or Homolytic Substitutions 36
XI. Cyclic Compounds through ß-Chlorovinyl Ketones 41
XII. Non-Transitional-Metal Vinyl Organometallic Compounds 45
XIII. Transition Metals and Metal Carbonyls 46
XIV. Ferrocene and Metallocenes 48
XV. Ligand Exchange in Ferrocene. Arene Cyclopentadienyl Derivatives of Iron 55
XVI. Cyclopentadienylmanganese Tricarbonyl and Cyclopentadienylrhenium Tricarbonyl 58
XVII. Organotitanium Compounds 61
XVIII. p-Allyl Complexes 63
XIX. s-Arylated Complexes 66
XX. p-Acetylene Complexes of Transition Metals 67
XXI. Conclusion 70
References 71
Chapter 2. Electronic Effects in Metallocenes and Certain Related Systems 90
I. Introduction 90
II. Homoannular Electronic Effects 91
III. Substituent Effects on the Ring-Metal Bond 102
IV. Substituent Effects on the Heteroatom. Oxidation-Reduction Potentials 109
V. Interannular Electronic Effects 112
VI. The Electronic Influence of Ferrocenyl and Related Groups as Substituents 118
VII. Conclusion 121
References 122
Chapter 3. Nitrogen Groups in Metal Carbonyl and Related Complexes 126
I. Introduction 126
II. Organonitrogen Derivatives 128
III. Derivatives of Inorganic Nitrogen Groups 179
References 197
Chapter 4. Infrared Intensities of Metal Carbonyl Stretching Vibrations 210
I. Introduction 210
II. Theory 212
III. Measurement 215
IV. Bonding 219
V. Solvents 222
VI. The Cotton-Kraihanzel Method 224
VII. The Method of Local Oscillating Dipoles 225
VIII. Bond Angles 227
IX. CKM and Intensities 229
X. Absolute Integrated Intensities 233
XI. Conclusion 243
References 244
Chapter 5. Organometallic Aspects of Diboron Chemistry 248
I. Introduction 248
II. Some General Features of Diboron Chemistry 249
III. Reactions of Diboron Tetrahalides with Unsaturated Compounds 262
IV. Properties of Some Diboration Products 276
References 280
Chapter 6. Organo–Transition Metal Chemistry—A Guide to the Literature 1950-1970 284
A. Textbooks 285
B. Reviews 292
C. Primary Journals 296
D. Abstracting Journals and Information Retrieval 299
E. Conference Reports 301
F. Synthesis 304
G. Compound and Formula Registers 306
References 307
Appendix 308
Chapter 7. Ligand Substitution in Transition Metal p-Complexes 358
I. Introduction 358
II. General Comments on Ligand Substitution in Complexes 359
III. p-Complexes with Ligands Stable in a Noncoordinated State 363
IV. p-Complexes with Ligands Unstable in a Noncoordinated State 382
V. Conclusion 420
References 420
Author Index 430
Author Index: Reviews of Organo-Transition Metal Chemistry 1950-1970 456
Subject Index 462
Cumulative Subject Index: Volumes 6-10 468
Cumulative List of Contributors 472
Cumulative List of Titles 473