Carbon Monoxide in Organic Synthesis

Bartolo Gabriele is Full Professor of Organic Chemistry at the Department of Chemistry and Chemical Technologies at the University of Calabria (UNICAL) in Italy since 2006. He has authored over 180 scientific publications and 20 industrial patents and received the "Synthetic Organic Chemistry Prize" from the Italian Chemical Society in 2013. His current research interests include the development of novel catalytic methods to produce high value-added molecules under sustainable conditions, the synthesis of heterocycles through annulation reactions, and the development of novel synthetic processes for carbon oxides reutilization.

1. Introduction: Carbon Monoxide as Synthon in Organic Synthesis
PART I: CARBONYLATIONS PROMOTED BY FIRST ROW TRANSITION METAL CATALYSTS
2. Cobalt-catalyzed Carbonylations
3. Nickel-catalyzed Carbonylations
4. Carbonylations Catalyzed by other First Row Transition Metal Catalysts (Manganese, Iron, Copper)
PART II: CARBONYLATIONS PROMOTED BY SECOND ROW TRANSITION METAL CATALYSTS
5. Ruthenium-catalyzed Carbonylations
6. Rhodium-catalyzed Carbonylations
7. Palladium(0)-catalyzed Carbonylations
8. Palladium(II)-catalyzed Carbonylations
9. Carbonylations Catalyzed by other Second Row Transition Metal Catalysts
PART III. MISCELLANEOUS CARBONYLATION REACTIONS
10. Carbonylations Promoted by Third Row Transition Metal Catalysts
11. Metal-free Carbonylation Processes
12. Conclusion and Perspectives