Properties of Gases, Liquids, and Solutions -

Properties of Gases, Liquids, and Solutions (eBook)

Principles and Methods

Warren P. Mason (Herausgeber)

eBook Download: PDF
2013 | 1. Auflage
494 Seiten
Elsevier Science (Verlag)
978-1-4832-7508-6 (ISBN)
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Physical Acoustics: Principles and Methods, Volume ll-Part A: Properties of Gases, Liquids, and Solutions ponders on high frequency sound waves in gases, liquids, and solids that have been proven as effective tools in examining the molecular, domain wall, and other types of motions.
The selection first offers information on the transmission of sound waves in gases at very low pressures and the phenomenological theory of the relaxation phenomena in gases. Topics include free molecule propagation, phenomenological thermodynamics of irreversible processes, and simultaneous multiple relaxation processes. The book then takes a look at relaxation processes in gases, as well as excitation relaxation, molecular theory of relaxation times, and relaxation of a dissociation equilibrium.
The manuscript surveys thermal, structural, and shear relaxation in liquids. Discussions focus on the basic theory for a single chemical reaction, structural viscosity, and cooperative effects on mechanical and dielectric processes. The book also underscores the propagation of ultrasonic waves in electrolytic solutions, including ultrasonic velocity and relaxation processes in electrolytic solutions.
The selection is highly recommended for readers interested in physical acoustics.
Physical Acoustics: Principles and Methods, Volume ll-Part A: Properties of Gases, Liquids, and Solutions ponders on high frequency sound waves in gases, liquids, and solids that have been proven as effective tools in examining the molecular, domain wall, and other types of motions. The selection first offers information on the transmission of sound waves in gases at very low pressures and the phenomenological theory of the relaxation phenomena in gases. Topics include free molecule propagation, phenomenological thermodynamics of irreversible processes, and simultaneous multiple relaxation processes. The book then takes a look at relaxation processes in gases, as well as excitation relaxation, molecular theory of relaxation times, and relaxation of a dissociation equilibrium. The manuscript surveys thermal, structural, and shear relaxation in liquids. Discussions focus on the basic theory for a single chemical reaction, structural viscosity, and cooperative effects on mechanical and dielectric processes. The book also underscores the propagation of ultrasonic waves in electrolytic solutions, including ultrasonic velocity and relaxation processes in electrolytic solutions. The selection is highly recommended for readers interested in physical acoustics.

Front Cover 1
Properties of Gases, 
4 
Copyright Page 5
Table of Contents 10
CONTRIBUTORS 6
PREFACE 8
CONTENTS OF VOLUME I—PART A 14
CONTENTS OF VOLUME I—PART B 15
Chapter 1. Transmission of Sound Waves in Gases at Very Low Pressures 20
I. Introduction 20
II. Nomenclature 22
III. Theory 26
IV. Experimental Methods 47
V. Results and Discussion 53
VI. Mixtures 54
VII. Free-Molecule Propagation 56
VIII. Appendix: Tables 59
REFERENCES 62
Chapter 2. Phenomenological Theory of the Relaxation Phenomena in Gases 66
List of Symbols 67
I. Introductory Remarks 69
II. The Phenomenological Thermodynamics of Irreversible Processes 71
III. Irreversible Processes in Homogeneous Closed Systems and in Free Acoustic Fields 74
IV. The Single Relaxation Process 80
V. Simultaneous Multiple Relaxation Processes 102
VI. Examples of Multiple Relaxations 121
REFERENCES 150
Chapter 3. Relaxation Processes in Gases 152
I. Problem Definition and Classification 152
II. Excitation Relaxation 154
III. Molecular Theory of Relaxation Times 201
IV. Relaxation of a Dissociation Equilibrium 212
REFERENCES 218
Chapter 4. Thermal Relaxation in Liquids 222
I. Introduction 222
II. Basic Theory for a Single Chemical Reaction 228
III. The Description and Interpretation of Experimental Results 246
ACKNOWLEDGMENTS 297
REFERENCES 298
Chapter 5. Structural and Shear Relaxation in Liquids 300
I. Introduction 301
II. Elastic Moduli of Liquids 304
III. Structural Viscosity 312
IV. Velocity Dispersion and Absorption Due to Shear and Structural Relaxation 334
V. High-Frequency Limiting Moduli of Liquids 338
VI. Relaxational Behavior of Moduli 348
VII. The Relation of Ultrasonic and Dielectric Relaxation Times 360
VIII. Cooperative Effects on Mechanical and Dielectric Processes 365
REFERENCES 367
Chapter 6. The Propagation of Ultrasonic Waves in Electrolytic Solutions 370
List of Symbols 370
I. Introduction 373
II. Ultrasonic Velocity 374
III. Relaxation Processes in Electrolytic Solutions 395
IV. Other Effects 472
ACKNOWLEDGMENTS 477
REFERENCES 477
Author Index 482
Subject Index 489

Erscheint lt. Verlag 22.10.2013
Sprache englisch
Themenwelt Naturwissenschaften Physik / Astronomie Mechanik
Technik
ISBN-10 1-4832-7508-6 / 1483275086
ISBN-13 978-1-4832-7508-6 / 9781483275086
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