Chemistry of Oxygen (eBook)

Front Cover 1
The Chemistry of Oxygen 4
Copyright Page 5
Table of Contents 6
PREFACE 8
22. OXYGEN 10
CHAPTER 1. OXYGEN 10
1.1. DISCOVERY OF OXYGEN 10
1.2. GENERAL 11
1.3. ISOTOPES OF OXYGEN 16
1.4. OCCURRENCE AND EXTRACTION 21
1.5. STRUCTURAL PROPERTIES 23
1.6. SPECTROSCOPIC PROPERTIES 26
1.7. MAGNETIC PROPERTIES 30
1.8. REACTIONS OF 02 34
1.9. REMOVAL OF 02 41
1.10. ANALYSIS 42
1.11. TOXIC EFFECTS OF AN EXCESS OF 0 2 42
1.12. PRODUCTION AND USES OF 02 43
CHAPTER 2. OXYGEN ATOMS AND IONS 44
2.1. ATOMIC OXYGEN 44
2.2. ION-MOLECULE REACTIONS 46
CHAPTER 3. OXIDES AS A CLASS 47
3.1. INTRODUCTION 47
3.2. ACID-BASE CHARACTER OF SIMPLE OXIDES 47
3.3. OXIDES AS A CLASS: STRUCTURES 54
3.4. ALLOTROPY OF OXIDES 64
3.5. THERMODYNAMIC CONSIDERATIONS 64
3.6. GEOMETRICAL EFFECTS 65
CHAPTER 4. WATER 66
4.1. PHYSICAL PROPERTIES 66
4.2. CHEMICAL PROPERTIES 72
CHAPTER 5. OXYGEN FLUORIDES 72
5.1. INTRODUCTION 72
5.2. OXYGEN DIFLUORIDE, OF2 73
5.3. OXYGEN MONOFLUORIDE, OF 76
5.4. DIOXYGEN DIFLUORIDE, O2F2 77
5.5. DIOXYGEN MONOFLUORIDE, O2F 81
5.6. ENERGETICS AND NUCLEAR MAGNETIC RESONANCE 83
5.7. TETRAOXYGEN DIFLUORIDE, O4F2, AND THE EQUILIBRIUM 04F202F 85
5.8. TRIOXYGEN DIFLUORIDE, O3F2 86
5.9. PENTAOXYGEN DIFLUORIDE, O5F2, AND HEXAOXYGEN DIFLUORIDE, O6F2 89
5.10. OTHER OXYGEN FLUORIDE POSSIBILITIES 89
5.11. COMPOUNDS OF CF3, FLUORINE AND OXYGEN 89
CHAPTER 6. HYDROGEN PEROXIDE229 96
6.1. HISTORY 96
6.2. SYNTHESIS 96
6.3. MOLECULAR STRUCTURE AND SPECTRA 97
6.4. OTHER PHYSICAL PROPERTIES 98
6.5. CHEMICAL PROPERTIES 100
6.6. ANALYTICAL CHEMISTRY 102
6.7. USES OF HYDROGEN PEROXIDE 102
CHAPTER 7. PEROXIDES AND RELATED COMPOUNDS 103
7.1. DIOXYGENYL SALTS 103
7.2. IONIC SUPEROXIDES257 104
7.3. IONIC PEROXIDES257 105
7.4. NON-STOICHIOMETRIC PEROXIDES259 105
7.5. PEROXIDES CONTAINING DIRECTED BONDS 105
7.6. OXYGEN CARRIERS280 109
7.7. RELATIONSHIPS BETWEEN BOND LENGTH AND BOND ORDER IN PEROXIDES AND RELATED COMPOUNDS 109
CHAPTER 8. OZONE AND RELATED SPECIES 110
8.1. OZONE 110
8.2. OZONIDES 113
CHAPTER 9. OTHER SPECIES CONTAINING O3 AND O4 GROUPS 117
9.1. O4 117
9.2. CHARGED O4 SPECIES 117
9.3. HYDROGEN SUPEROXIDES359 118
9.4. OTHER TRIOXIDES AND TETROXIDES 118
Contents of Comprehensive Inorganic Chemistry 120
INDEPENDENT OPINION 122
INDEX 124