Structural and Electronic Paradigms in Cluster Chemistry -

Structural and Electronic Paradigms in Cluster Chemistry

D.M.P. Mingos (Herausgeber)

Buch | Softcover
XII, 211 Seiten
2013 | 1. Softcover reprint of the original 1st ed. 1997
Springer Berlin (Verlag)
978-3-662-14816-7 (ISBN)
53,49 inkl. MwSt
It is 25 years since the seminal papers describing the relationships between the skeletal geometrics and closed shell electronic requirements of metal clusters were originally published. The electron counting rules which developed from these papers, are now to be found in all undergraduate inorganic textbooks. This volume provides a contemporary account of recent applications of the methodology and the mathematical foundations of the rules. In addition it describes how it is possible to accomondate acception to the rules within a wider framework. The authors are the foremost authorities in the field and give a broad introduction to the area.

Mathematical cluster chemistry.- Metal-metal interactions in transition metal clusters with ?-donor ligands.- Electron count versus structural arrangement in clusters based on a cubic transition metal core with bridging main group elements.- Metallaboranes.- Clusters with interstitial atoms from the p-block: How do Wade's rules handle them?.- Diverse naked clusters of the heavy main-group elements. Electronic regularities and analogies.

Erscheint lt. Verlag 3.10.2013
Reihe/Serie Structure and Bonding
Co-Autor J.D. Corbett, M.-F. Fan, T.P. Fehlner, J.-F. Halet, C.E. Housecroft, R.L. Johnston, Z. Lin, J.-Y. Saillard
Zusatzinfo XII, 211 p. 84 illus.
Verlagsort Berlin
Sprache englisch
Maße 155 x 235 mm
Gewicht 349 g
Themenwelt Naturwissenschaften Chemie Anorganische Chemie
Naturwissenschaften Physik / Astronomie Atom- / Kern- / Molekularphysik
Schlagworte Bonding • Borane • boranes • Chemische Bindung • Cluster • clusters • electron counting rules • nackte Cluster • naked clusters • polyhedrale Moleküle • polyhedrale Skelettelektronpaartheorie • polyhedral molecules • polyhedral skeletal electron pair theory • Valenzel • Valenzelektronen-Regel • Wade/Mingos Regel • Wade/Mingos rules
ISBN-10 3-662-14816-1 / 3662148161
ISBN-13 978-3-662-14816-7 / 9783662148167
Zustand Neuware
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